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Narayan Das Soumen De Nantu Sarkar 《Mathematical Methods in the Applied Sciences》2020,43(3):1313-1336
The generalized thermoelasticity theory based upon the Green and Naghdi model III of thermoelasticity as well as the Eringen's nonlocal elasticity model is used to study the propagation of harmonic plane waves in a nonlocal thermoelastic medium. We found two sets of coupled longitudinal waves, which are dispersive in nature and experience attenuation. In addition to the coupled waves, there also exists one independent vertically shear-type wave, which is dispersive but experiences no attenuation. All these waves are found to be influenced by the elastic nonlocality parameter. Furthermore, the shear-type wave is found to face a critical frequency, while the coupled longitudinal waves may face critical frequencies conditionally. The problem of reflection of the thermoelastic waves at the stress-free insulated and isothermal boundary of a homogeneous, isotropic nonlocal thermoelastic half-space has also been investigated. The formulae for various reflection coefficients and their respective energy ratios are determined in various cases. For a particular material, the effects of the angular frequency and the elastic nonlocal parameter have been shown on phase speeds and the attenuation coefficients of the propagating waves. The effect of the elastic nonlocality on the reflection coefficients and the energy ratios has been observed and depicted graphically. Finally, analysis of the various results has been interpreted. 相似文献
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Mufida M. Hmaida 《代数通讯》2020,48(9):3962-3972
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After constructing the Bethe state of the XXZ Gaudin model with generic non-diagonal boundary terms,we analyze the properties of this state and obtain the determinant representations of the scalar products for this XXZ Gaudin model. 相似文献
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Abstract The relative toxicity of selected industrial organic chemicals was secured from the literature for the static 48-h Tetrahymena pyriformis 50% population growth impairment and the flow-through 96-h Pimephales promelas 50% mortality endpoints. Chemicals were selected to represent the nonpolar narcosis (aliphatic alcohols and aliphatic ketones) and polar narcosis (anilines and phenols) mechanisms of toxic action. molar volume (MV) and 1-octanol/water partition coefficient (log K ow) data were generated for each chemical. High-quality, log K ow dependent quantitative structure-activity relationships were observed for each chemical class and mechanism of action for both endpoints. The volume fraction (V t) for each chemical in the target phase was determined from the toxicant concentration in the water (toxicity data), the MV, and the target/water partition coefficient (K tw) with K tw considered equal to K ow (1-a). Analyses of target sites, by way of “a” revealed that “a” was constant for a mechanism of action regardless of chemical class, but distinct for a given test system. Mean V t was constant for each mechanism of action regardless of chemical class or test system. These results suggest, at least for reversible physical mechanisms, that volume fraction analyses are significant in determining the mechanism of toxic action of a chemical. 相似文献
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Quantitative structure-activity relationships (QSARs) based on the octanol/water partition coefficient were employed to predict acute toxicities of 36 substituted aromatic compounds and their mixtures. In this study, the model developed by Verhaar et al. was modified and used to calculate octanol/water partition coefficients of chemical mixtures. To validate the model, acute toxicities of these chemicals were measured to Vibrio fischeri in terms of EC50. The results indicated that the obtained QSAR models could be used to predict toxicities of samples consisting of these substituted aromatic compounds, individually or in combinations. The obtained equations were proved to be robust enough by using the leave-one-out test method. By classifying these chemicals into two groups, polar and non-polar, the toxicities of chemical mixtures within each group can be predicted accurately from their calculated partition coefficients. 相似文献
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Erland L. Nordgård Jamil Ahmad Johan Sjöblom 《Journal of Dispersion Science and Technology》2013,34(6):871-880
The oil-water partitioning of a synthetic tetraacid acting as a model compound for indigenous C80-C82 ARN acids has been studied as a function of pH, ionic strength and type of monovalent counterion. Experimental data obtained with ultraviolet-visible and HPLC/UV analyses have been fitted to thermodynamic models based on one, two or four dissociation steps to obtain o/w partition coefficients (K wo ) of the fully protonated acid between chloroform and aqueous solutions, and its apparent acidity constant(s), pK a. As the study is conducted above the CMC of the tetraacid, in general high apparent acidity constants were obtained in the range from 6 to 8 resulting from micellization equilibria. K wo values were obtained in the range from 10?3 to 10?4, and decreasing with increasing salinity. At 50 mM K+, no conclusions could be made regarding the number of distinguishable dissociation steps, while at higher ionic strength (184 mM and 452 mM K+) and at 184 mM Na+ a model with two dissociation steps provided good fits to the experimental data. The first step was found to be given by a pK a ≈ 6.6–6.8 and the second dissociation step at pK a values ≈ 7.8–8.3. The two-step mechanism supports previous results obtained by potentiometric titrations. No significant difference in the o/w behavior was observed when changing the counterion from potassium to sodium. The main partitioning of the tetraacid in the aqueous phase occurred above pH 8, where the fully deprotonated acid was formed. 相似文献